Profitability Index (PI) or Benefit-Cost Ratio measures the ratio of the present value of expected cash flows of a project to its initial investment:
$$PI = \frac{\sum_{i=1}^{t}\frac {C_{i}}{(1+r)^{i}}}{C_{0}}$$
C0β initial investment;
rβ discount rate (e.g., weighted average cost of capital);
tβ number of periods.
Essentially, the profitability index is a percentage or ratio form of NPV.
General decision rules for using the Profitability Index method:
The profitability index measures the value created per unit of invested capital using discounted cash flows.
A PI above 1 usually means the project is expected to create value, while a PI below 1 suggests rejection.